Influencia de las condiciones de operación en la producción de hidrógeno por reformado de metanol: aproximación numérica
Palabras clave:
Reformado de metanol, Producción de hidrógeno, Plug modelo reactor
Resumen
Este trabajo describe el estudio unidimensional del proceso de reformado de metanol en cortos tiempos modificados de residencia. El proceso Reformado de metanol es importante para la producción de hidrógeno como vector energético. Un modelo matemático 1-D del reactor es desarrollado. Se adopta el mecanismo cinético de Peppley (1999). Las predicciones numéricas muestran la misma tendencia de los datos experimentales. Un análisis de sensibilidad de las variables significativas del proceso es realizado (presión, relación CH3OH/H2O y temperatura).
Referencias bibliográficas
[1] Amphlett JC, Creber KAM, Davis JM, Mann RF, Peppley BA, Stokes DM. Hydrogen production by steam reforming of methanol for polymer electrolyte fuel cells. Int J Hydrogen Energy. 19:131-137. 1994.
[2] Mathiak J, Heinzel A, Roes J, Kalk T, Kraus H, Brandt H. Coupling of a 2.5 kW steam reformer with a 1 kWel PEM fuel cell. J Power Sources. 131:112-119. 2004.
[3] Hong-Yue Tang, Jason Greenwood, Paul Erickson. Modeling of a fixed-bed copper-based catalyst for reforming methanol: Steam and autothermal reformation. 40, 8034-8050. 2015.
[4] L. Pacheco, D. Della-Valle, O. Le Corre, H. Habchi, T. Lemenand, H. Peerhossaini, “Modeling open flow steam reforming of metanol over Cu/ZnO/Al2O3 vatalyst in an axisymmetric reactor”. Journ. Appl. Fluid Mechanics.Vol 8, No 1, pp 33-42. 2015.
[5] Peppley B.A., J.C. Amphlett, L.M. Kearns, R.F. Mann, “Methanol-steam reforming on Cu/ZnO/AL2O3. Part 1: the reaction network”. Appl. Catal. A: Gen. 179,21-29. 1999a.
[6] Peppley B.A., J.C. Amphlett, L.M. Kearns, R.F. Mann, “Methanol-steam reforming on Cu/ZnO/AL2O3 catalysts. Part 2: A comprehensive kinetic model”. Appl. Catal. A: Gen 179, 31-49. 1999b.
[7] Zhao T., K-D. Krever, T. Van-Nguyen, “Advances in Fuel Cells”. Elsevier Ltd. 2007.
[8] Takeguchi T., Y. Kni, M. Inoue, K. Eguchi, “Steam reforming of methanol on copper catalysts supported on large-surface-area ZnAl2O3”, Catal. Lett. 83 Nos 1-2. 2002.
[9] Agrell J., H. Birgersson, M. Boutonnet, “Steam reforming of methanol over a Cu/ZnO/Al2O3 catalyst: a kinetic and strategies for suppression of CO formation”. J. of Power Sources 106, 249-257. 2002.
[10] Jiang C.J., D.L. Trimm, M.S. Wainwright, “Kinetic study of steam reforming of methanol over copper-based catalysts”. Appl. Catal. A: Gen. 93,245-255. 1993.
[11] Ranganathan E.S., S.K. Bej, L.T. Thompson,” A methanol steam reforming over Pd/ZnO and Pd/CeO2 catalysts”. Appl. Catal. 289,153-162. 2005.
[12] Purnama H., T. Ressler, R.E. Jentoft, H. Soerijanto, R. Schlögl, R. Schomäcker, “CO formation/selectivity for steam reforming of methanol with a commercial CuO/ZnO/Al2O3 catalyst”. Appl. Catal. A: Gen. 259,83-94. 2004.
[13] A. Iulianelli, P. Ribeirinha, A. Mendes, A. Basile. Methanol steam reforming for hydrogen generation via conventional and membrane reactors: A review. Renewable and sustainable Energy Reviews. 29, 355-368. 2014.
[14] Jiang C.J., D.L. Trimm, M.S. Wainwright, Kinetic mechanism for the reaction between methanol and water over a Cu/ZnO/Al2O3, Appl. Catal. A: Gen. 97,145-158. 1993b.
[15] S.T. Yong, C.W. Ooi, S.P. Chai, X.s. Wu. Review of methanol reforming-Cu-based catalysts, surface reaction mechanisms, and reaction schemes. International Journal of hydrogen energy. 30, 9541-9552. 2013.
[2] Mathiak J, Heinzel A, Roes J, Kalk T, Kraus H, Brandt H. Coupling of a 2.5 kW steam reformer with a 1 kWel PEM fuel cell. J Power Sources. 131:112-119. 2004.
[3] Hong-Yue Tang, Jason Greenwood, Paul Erickson. Modeling of a fixed-bed copper-based catalyst for reforming methanol: Steam and autothermal reformation. 40, 8034-8050. 2015.
[4] L. Pacheco, D. Della-Valle, O. Le Corre, H. Habchi, T. Lemenand, H. Peerhossaini, “Modeling open flow steam reforming of metanol over Cu/ZnO/Al2O3 vatalyst in an axisymmetric reactor”. Journ. Appl. Fluid Mechanics.Vol 8, No 1, pp 33-42. 2015.
[5] Peppley B.A., J.C. Amphlett, L.M. Kearns, R.F. Mann, “Methanol-steam reforming on Cu/ZnO/AL2O3. Part 1: the reaction network”. Appl. Catal. A: Gen. 179,21-29. 1999a.
[6] Peppley B.A., J.C. Amphlett, L.M. Kearns, R.F. Mann, “Methanol-steam reforming on Cu/ZnO/AL2O3 catalysts. Part 2: A comprehensive kinetic model”. Appl. Catal. A: Gen 179, 31-49. 1999b.
[7] Zhao T., K-D. Krever, T. Van-Nguyen, “Advances in Fuel Cells”. Elsevier Ltd. 2007.
[8] Takeguchi T., Y. Kni, M. Inoue, K. Eguchi, “Steam reforming of methanol on copper catalysts supported on large-surface-area ZnAl2O3”, Catal. Lett. 83 Nos 1-2. 2002.
[9] Agrell J., H. Birgersson, M. Boutonnet, “Steam reforming of methanol over a Cu/ZnO/Al2O3 catalyst: a kinetic and strategies for suppression of CO formation”. J. of Power Sources 106, 249-257. 2002.
[10] Jiang C.J., D.L. Trimm, M.S. Wainwright, “Kinetic study of steam reforming of methanol over copper-based catalysts”. Appl. Catal. A: Gen. 93,245-255. 1993.
[11] Ranganathan E.S., S.K. Bej, L.T. Thompson,” A methanol steam reforming over Pd/ZnO and Pd/CeO2 catalysts”. Appl. Catal. 289,153-162. 2005.
[12] Purnama H., T. Ressler, R.E. Jentoft, H. Soerijanto, R. Schlögl, R. Schomäcker, “CO formation/selectivity for steam reforming of methanol with a commercial CuO/ZnO/Al2O3 catalyst”. Appl. Catal. A: Gen. 259,83-94. 2004.
[13] A. Iulianelli, P. Ribeirinha, A. Mendes, A. Basile. Methanol steam reforming for hydrogen generation via conventional and membrane reactors: A review. Renewable and sustainable Energy Reviews. 29, 355-368. 2014.
[14] Jiang C.J., D.L. Trimm, M.S. Wainwright, Kinetic mechanism for the reaction between methanol and water over a Cu/ZnO/Al2O3, Appl. Catal. A: Gen. 97,145-158. 1993b.
[15] S.T. Yong, C.W. Ooi, S.P. Chai, X.s. Wu. Review of methanol reforming-Cu-based catalysts, surface reaction mechanisms, and reaction schemes. International Journal of hydrogen energy. 30, 9541-9552. 2013.
Cómo citar
Pacheco Sandoval, L. E., Díaz González, C. A., Jaimes Reatiga, L. E., Carrillo, L. J., & Díaz Joven, B. A. (2017). Influencia de las condiciones de operación en la producción de hidrógeno por reformado de metanol: aproximación numérica. Revista Colombiana De Computación, 18(2), 22–32. Recuperado a partir de https://revistas.unab.edu.co/index.php/rcc/article/view/3215
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Publicado
2017-12-01
Sección
Artículo de investigación científica y tecnológica
